Sustainable Utilization of Snail Shell Powder and Marble Dust in Formulating Alkyd Paints for Industrial Applications


Authors : Isaac Ogbennaya Igwe; Daberechi Mishack Ebonine; Ifeoma Perpetua Oragwu; Chinedu Kingson Adindu; Emmanuel Chidiebube Onyema; Amarachukwu Prince Mbanefo; Fabian Chinonye Onunwa; Ukeme James Timothy

Volume/Issue : Volume 9 - 2024, Issue 11 - November


Google Scholar : https://tinyurl.com/bdcufj52

Scribd : https://tinyurl.com/vr978w7b

DOI : https://doi.org/10.5281/zenodo.14436269


Abstract : Alkyd paints based on snail shell powder, and marble dust extenders were formulated at extender contents, 0 - 80 wt. %. Titanium dioxide (TiO2) formulated paint served as the reference paint. The formulated paints exhibited satisfactory drying, impact resistance, and adhesion properties with the paint sample containing 60 wt.% snail shell powder exhibiting the least dry film removal of 6.25%. The sample containing 60 wt.% marble dust exhibited the best pencil hardness of 5H. The thickness of the dry paint films (0.20 - 0.30 mm) indicated the paints potentials to function as anti - corrosive paints. The paint viscosities increased with extender content, and snail shell powder formulated paints exhibited higher viscosities than those of marble dust. The paint samples containing 20 - 40 wt.% extenders exhibited high gloss that is suitable for automobile, and other consumer goods applications. The dry paint films were generally unaffected in 3% NaCl, and 3% H2SO4.

Keywords : Snail Shell Powder, Alkyd Paint, Marble Dust, Extender, Impact Resistance.

References :

  1. Yang Q, Yuan F, Xu L, Yan Q, Yang Y, Wu D, Guo F, Yang GS (2019). An update of moisture barrier coating for drug delivery. Pharmaceutics 11(9): 436.
  2. Bollhorst T, Rezwan K, Maas M (2017). Colloidal capsules: nano - and microcapsules with colloidal particle shells. Chem Soc Rev 46(8): 2091-2126.
  3. The demand for coatings raw materials to 2022. www.paint.org>articles>demand Accessed 30 Sept 2024.
  4. Chen X, Mao SS (2007). Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107(7):2891-2959.
  5. Gogte BB (1994). Fly ash - based coatings. Paintindia XLIV (10):51-56.
  6. Youssef EAM, Nivim M, Abd El ‐ Ghaffar MA (1998). Characterization and evaluation of silica fumes as an extender pigment for surface coating application. Pigment Resin technol 27:88 - 98.
  7. Saxena M, Dhimole LK (2005). Utilization and value addition of copper tailing as an extender for development of paints. J hazard mater 129(1-3):50 - 57.
  8. Ewulonu CM, Igwe IO, Onyeagoro GN (2016). Performance of local clay - titanium dioxide core - shell extender pigments in alkyd paints. Adv nanoparticles 5: 90 -102.
  9. Onunwa FC, Aharanwa BC, Anyanwu PI, Akanbi MN, Igwe IO (2024). Evaluation of sustainable eco -friendly paints based on Oguta clay for industrial applications. Aust J Sci Technol 8(3):49 - 55.
  10. Narayan R, Raju KV (2000). The use of calcined clay as part replacement of titanium dioxide in latex paint formulations. J Appl Polym Sci 77:1029 - 36.
  11. Youssef EA (2002). Characterization, surface modification, and evaluation of Egyptian dolomite ore as an extender pigment for paint. Pigment Resin technol 13:226 - 33.
  12. Farzaneh A, Mohammadi M, Yazdani E, Falahati M (2019). Effects of different types and concentrations of mineral extenders on main properties of long oil alkyd paint with titanium dioxide pigment. Prog Org Coat 134: 316 - 324.
  13. Anyiam C, Igwe I O (2012). Studies on the use of an industrial waste clay in alkyd paint formulations. Int J of Acad Res 4(2): 15 - 23.
  14. Inci M, Karademir D, Ülkü S, Turgut H, Turgut G (2017). Effects of partial substitution of titanium dioxide (TiO2) with different extenders on architectural interior paint properties. J Coat Technol Res 14(1): 153-160.
  15. Igwe IO, Acha FN, Agwu GI, Ifeacho VC, Okonkwo SN, Ekwueme CC, Igboanugo UI (2021). Utilization of granite quarry dust extender in formulating anti - corrosive paints for the protection of steel. Aust J Sci Technol 5(3): 631 - 637.
  16. Adewole MB, Adesina MA (2011). Impact of marble mining on soil properties in a part of Guinea Savanna zone of Southwestern Nigeria (2011) Ethiopian J Environ Studies Manag 4(2):1 - 8.
  17. Bakash P, Pappu A, Patidar R, Gupta MK, Thakur VK (2020). Transforming marble waste into high-performance, water-resistant, and thermally insulative hybrid polymer composites for environmental sustainability. Polymers 12:1781.
  18. Awad AH, Aly Abd El-Wahab A, El - Gamsy R, Abdel - Latif MH (2019). A study of some thermal and mechanical properties of HDPE blend with marble and granite dust. Ain Shams Eng 10:353 – 358.
  19. Cinar M, Kar F (2018). Characterization of Composites produced from waste PET and marble dust. Constr Build Mater 163, 734 – 741.
  20. Martínez - Barrera G, Menchaca - Campos C, Gencel O (2013). Polyester polymer concrete: Effect of the marble particle sizes and high gamma radiation doses. Constr Build Mater 41:204 - 208.
  21. Awad AH, Abdelghany A, Abd El-Wahab AA, Elgamasy R, Abdellatif MH (2020). The influence of adding marble and granite dust on the mechanical and physical properties of PP composites. J Therm Anal Calorim 6:2615 - 2623.
  22. Awad AH, Abdellatif MH (2019). Assessment of mechani.cal and physical properties of LDPE reinforced with marble dust. Compos Part B: Eng 173:106948.
  23. Ahmed K, Nizami SS, Raza NZ, Shirin K (2012). Cure characteristics, mechanical and swelling properties of marble sludge filled EPDM modified chloroprene rubber blends. Adv Mater Phys Chem 2(2):90 - 97.
  24. Kumar D, Posinasetti NR, Dangayach GS (2016). An investigation on optimization of parameters for injection molded polypropylene-marble composites with multi objective genetic algorithm. In: Proceedings of the 2016 International Conference on Recent Advances and Innovations in Engineering (ICRAIE), Jaipur, India 23 – 25.
  25. Karaşa - hin M, Terzi S (2007). Evaluation of marble waste dust in the mixture of asphaltic concrete. Constr Build Mater 21(3):616 - 620.
  26. Martins P, Brito JD, Rosa A, Pedro D (2014). Mechanical performance of concrete with incorporation of coarse waste from the marble industry. Mater Res 17:1093 - 1101.
  27. Kore SD, Vyas AK (2016). Impact of marble waste as coarse aggregate on properties of lean cement concrete. Case Stud Constr Mater 4:85 - 92
  28. Aruntaş HY, Gürü M, Dayı M, Tekin I (2010) Utilization of waste marble dust as an additive in cement production. Mater Des 31(8):4039 - 4042.
  29. Pruncu C, Vladescu A, Hynes RJ, Sankaranarayanan R (2022). Surface investigation of physella acuta snail shell particle reinforced aluminium matrix composites. Coatings 12(6):794.
  30. Kolawole MY, Aweda JO, Abdulkareem S (2017). Archachatina marginata bio - shells as reinforcement material in metal - matrix composites. Int J Auto Mech Eng 14(1):4068 - 4079.
  31. Udeozor SO, Evbuomwan BO (2014). The effectiveness of snail shell as adsorbent for the treatment of waste water from beverage industries using H3PO4 as activating agent. Int Org Sci Res J Eng 4(8):37 - 41.
  32. Gumus RH, Okpeku I (2015). Production of activated carbon and characterization from snail shell waste (Helix Promatia). Adv Chem Eng Sci 5:51 - 61.
  33. Igwe IO, Ejim AA (2011). Studies on mechanical and end - use properties of natural rubber filled with snail shell powder. Mat Sci Appl 2:801 - 809.
  34. Igwe IO, Nwapa C, Ekwueme CC, Odoala C, Madumere GC, Marc DE,…. Ogbogu MC (2024). Study of mechanical and water absorption properties of marble dust - reinforced unsaturated polyester resin concretes. Aust J Sci Technol 8(2):10 – 14.
  35. Igwe IO (2007). Studies on the properties of polypropylene filled with agricultural and domestic wastes. J Res Eng 4(2):9 - 13.
  36. Igwe IO, Oragwu IP, Nwapa C (2024). Analysis of sustainable polyester tiles of domestic waste. J Polym Sci Technol 8(1): 15 – 23.
  37. Igwe IO, Acha FN, Agwu GI, Ifeacho VC, Okonkwo SN, Ekwueme CC, Igboanugo UI (2021). Utilization of granite quarry dust extender in formulating anti – corrosive paints for the protection of steel. Aust J Sc Technol 5(3): 631 – 637.
  38. Onunwa FC, Aharanwa BC, Anyanwu PI, Akanbi MN, Igwe IO (2024). Evaluation of sustainable eco – friendly alkyd paints based on Oguta clay for industrial applications. Aust J Sc Technol 8(3): 49 – 55.
  39. Tan Tian Aik D (1995). Durability and TiO2 pigments. Paintindia Annual J 44: 84 – 93.
  40. Nigerian Industrial Standards (NIS) (1989). Standards for paints and varnishes Part 3. Lagos: Nigerian Industrial Standards.

Alkyd paints based on snail shell powder, and marble dust extenders were formulated at extender contents, 0 - 80 wt. %. Titanium dioxide (TiO2) formulated paint served as the reference paint. The formulated paints exhibited satisfactory drying, impact resistance, and adhesion properties with the paint sample containing 60 wt.% snail shell powder exhibiting the least dry film removal of 6.25%. The sample containing 60 wt.% marble dust exhibited the best pencil hardness of 5H. The thickness of the dry paint films (0.20 - 0.30 mm) indicated the paints potentials to function as anti - corrosive paints. The paint viscosities increased with extender content, and snail shell powder formulated paints exhibited higher viscosities than those of marble dust. The paint samples containing 20 - 40 wt.% extenders exhibited high gloss that is suitable for automobile, and other consumer goods applications. The dry paint films were generally unaffected in 3% NaCl, and 3% H2SO4.

Keywords : Snail Shell Powder, Alkyd Paint, Marble Dust, Extender, Impact Resistance.

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe