Evaluation of Borax as an Alternative to Mercury in Gold Recovery: A Case Study of Benishangul Gumuz Region, Assosa Area, Western Ethiopia


Authors : Zeryihun Hailu Gebremariam; Dr. Bisrat Kebede Negwo

Volume/Issue : Volume 10 - 2025, Issue 11 - November


Google Scholar : https://tinyurl.com/bd3x2y9a

Scribd : https://tinyurl.com/yck4zr5s

DOI : https://doi.org/10.38124/ijisrt/25nov944

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.

Note : Google Scholar may take 30 to 40 days to display the article.


Abstract : Artisanal and small-scale gold mining (ASGM) is important to the Ethiopian economy, especially in the Benishangul Gumuz Region. But ASGM also uses mercury extensively during gold recovery, raising public and environmental health concerns. This study assesses the feasibility of using borax as an alternative to mercury for gold extraction. Comparisons focused on a series of ore samples collected from quartz-vein-hosted primary ore and placer gold deposits in the Assosa area. Wilcoxon Signed-Rank tests, ANOVA, and descriptive statistics were employed to collectively analyze gold recoveries by methodologies, borax smelting and mercury amalgamation. Results showed that borax smelting significantly improved gold yield, with a mean recovery of 0.6125 g compared to 0.2345 g with mercury. The results also found borax was technically, economically, and safely viable. This study recommends adoption of this method within ASGM in Ethiopia and suggests further funding for the study of borax, including further recommendations for mandated policies and further research into the future long-term environmental impacts of borax and its scalability.

Keywords : Borax Smelting; Mercury-Free Gold Recovery; Artisanal and Small-Scale Gold Mining; Environmental Sustainability; Benishangul Gumuz; Ethiopia.

References :

  1. Abu-Alam, T., Abd El Monsef, M., & Grosch, E. G. (2018). Shear-zone hosted gold mineralization of the Arabian–Nubian Shield: Devolatilization processes across the greenschist–amphibolite-facies transition. Geological Society, London, Special Publications, 478, 213–232.
  2. Appel, P. W. U., & Na-Oy, L. (2012). The borax method of gold extraction for small-scale miners. Blacksmith Institute Journal of Health and Pollution, 2(3), 5–10.
  3. Appel, P. W. U., & Na-Oy, L. D. (2014). Mercury-free gold extraction using borax for small-scale gold miners. Journal of Environmental Protection, 5(6), 493–499.
  4. Bedassa, A. (2014). Geology, geochemistry and genesis of gold mineralization in Ashashire prospect, Benishangul–Gumz region, western Ethiopia (Master’s thesis). Addis Ababa University, School of Earth Sciences.
  5. Bekele, B. (2022). Assessing the effects of gold mining on environment: A case study of Shekiso district, Guji zone, Ethiopia. Heliyon, 8(11), e11882.
  6. Belachew, G. (2023). Characterization of ore and gangue mineralogy at the Ashashire gold deposit, Benishangul-Gumuz Region, Western Ethiopia (Master’s thesis). Addis Ababa University, Addis Ababa Institute of Technology, Center for Ethio-mines Development.
  7. Clarkson, T. W., & Magos, L. (2006). The toxicology of mercury and its chemical compounds. Critical Reviews in Toxicology, 36(8), 609–662.
  8. Debele, D. J., & Koeberl, C. (2004). Geochemistry, alteration, and genesis of gold mineralization in the Okote area, southern Ethiopia. Geochemical Journal, 38, 307–331.
  9. Driscoll, C. T., Mason, R. P., Chan, H. M., Jacob, D. J., & Pirrone, N. (2013). Mercury as a global pollutant: Sources, pathways, and effects. Environmental Science & Technology, 47(10), 4967–4983.
  10. Gelaye, Y. (2022). Public health and economic burden of heavy metals in Ethiopia: Review. Heliyon, 10(10), e39022.
  11. Gibb, H., & O’Leary, K. G. (2014). Mercury exposure and health impacts among individuals in the artisanal and small-scale gold mining community: A comprehensive review. Environmental Health Perspectives, 122(7), 667–672.
  12. Hilson, G., & Pardie, S. (2006). Mercury: An agent of poverty in Ghana’s small-scale gold-mining sector? Resources Policy, 31(2), 106–116.
  13. Kabeta, M., Cheru, M. S., & Berhe, G. G. (2024). Applicability of gravity separation method on the Ashashire gold ore deposit from Benishangul Gumuz Region, Western Ethiopia. International Journal of Nonferrous Metallurgy, 11, 21–31.
  14. Oljira, T., Okunlola, O. A., Olatunji, A. S., Ayalew, D., & Ayele, B. (2022). Petrogenesis of the Neoproterozoic rocks of Megele area, Asosa, Western Ethiopia. Earth Sciences Research Journal, 26(2), 157–172.
  15. Spiegel, S. J., & Veiga, M. M. (2010). International guidelines on mercury management in small scale gold mining. Journal of Cleaner Production, 18(4), 375–385.
  16. Spiegel, S. J., Agrawal, S., Mikha, D., Veiga, M. M., Konolius, K., & Paul, B. (2018). Phasing out mercury? Ecological economics and Indonesia’s small-scale gold mining sector. Ecological Economics, 144, 1–11.
  17. Tariku, S. (2021). Environmental and socio-economic impact of artisanal and small-scale placer gold mining at Dima, Gambella, Ethiopia (Master’s thesis). Addis Ababa University.
  18. Teku, D. (2025). Geo-environmental and socio-economic impacts of artisanal and small-scale mining in Ethiopia: Challenges, opportunities, and sustainable solutions. Frontiers in Environmental Science, 13, 1505202.
  19. United Nations Environment Programme (UNEP). (2013). Minamata Convention on Mercury: Text and annexes. Geneva: UNEP.
  20. Veiga, M. M., Angeloci, G., Hitch, M., & Velasquez-López, P. C. (2014). Processing centres in artisanal gold mining. Journal of Cleaner Production, 64, 535–544.
  21. Wahed, M. A. E., Zoheir, B., Pour, A. B., & Kamh, S. (2021). Shear-related gold ores in the Wadi Hodein shear belt, South Eastern Desert of Egypt: Analysis of remote sensing, field and structural data. Minerals, 11(5), 474.
  22. Wondera, N. (2017). Petrogenesis of granitoid rocks of Assosa area, Western Ethiopia (Master’s thesis). Addis Ababa University, School of Earth Sciences.
  23. Zeleke, N., Tesso, A., & Bedemo, A. (2024). Impacts of mining projects on food security of households in Ethiopia: Empirical evidence from Benishangul-Gumuz Region. Frontiers in Sustainable Food Systems, 8, 1481827.
  24. Zhao, K., Yao, H., Wang, J., Ghebretnsae, G. F., Xiang, W., & Xiong, Y. Q. (2019). Genesis of the Koka gold deposit in Northwest Eritrea, NE Africa: Constraints from fluid inclusions and C–H–O–S isotopes. Minerals, 9(4), 201.

Artisanal and small-scale gold mining (ASGM) is important to the Ethiopian economy, especially in the Benishangul Gumuz Region. But ASGM also uses mercury extensively during gold recovery, raising public and environmental health concerns. This study assesses the feasibility of using borax as an alternative to mercury for gold extraction. Comparisons focused on a series of ore samples collected from quartz-vein-hosted primary ore and placer gold deposits in the Assosa area. Wilcoxon Signed-Rank tests, ANOVA, and descriptive statistics were employed to collectively analyze gold recoveries by methodologies, borax smelting and mercury amalgamation. Results showed that borax smelting significantly improved gold yield, with a mean recovery of 0.6125 g compared to 0.2345 g with mercury. The results also found borax was technically, economically, and safely viable. This study recommends adoption of this method within ASGM in Ethiopia and suggests further funding for the study of borax, including further recommendations for mandated policies and further research into the future long-term environmental impacts of borax and its scalability.

Keywords : Borax Smelting; Mercury-Free Gold Recovery; Artisanal and Small-Scale Gold Mining; Environmental Sustainability; Benishangul Gumuz; Ethiopia.

CALL FOR PAPERS


Paper Submission Last Date
31 - December - 2025

Video Explanation for Published paper

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe