Effect of Nano-Refractory Bricks on the Morphological and Thermal Properties of PVC/LDPE Polymer Blend


Authors : Aboalqasim Alqat; Mabrouk Makuaf; Hana Jamhour; Taha Hameda

Volume/Issue : Volume 10 - 2025, Issue 6 - June


Google Scholar : https://tinyurl.com/2yp9v2zd

DOI : https://doi.org/10.38124/ijisrt/25jun622

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : In this study, the morphological and thermal properties of a blend consisting of 75% polyvinyl chloride (PVC) and 25% low-density polyethylene (LDPE), reinforced with nano-refractory bricks (NRB) at varying ratios (1%, 3%, 5%, and 7%), were prepared and investigated. The objective was to enhance the blend’s thermal stability and surface structure homogeneity. The morphological structure of the prepared samples was analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The obtained images revealed that the nano-refractory brick particles remained predominantly within the PVC phase, resulting in an increased composite density without significantly affecting the LDPE phase. This suggests that the overall morphology of the composite is largely unaffected by the presence of the nano-refractory bricks. From a thermal perspective, thermogravimetric analysis (TGA/DTG) was conducted on all samples from room temperature up to 600 °C at a heating rate of 10 °C/min. FTIR and TGA results indicated that the decomposition onset temperature shifted to higher values due to the presence of nano-refractory bricks, with the most pronounced shift observed in the sample containing 3% reinforcement. Additionally, the rate of mass loss was reduced. These findings demonstrate that reinforcing the PVC/LDPE blend with nano-refractory bricks improves its performance, making it more suitable for applications that demand enhanced thermal and mechanical properties, such as those in the construction and electronics industries.

Keywords : Nano-Refractory Bricks, Low Density Polyethylene, Polymer, Thermal Properties.

References :

  1. Matsumoto, A. (2001). Polymerization of multiallyl monomers. Progress in Polymer Science, 26(2), 189-257.
  2. Kiparissides, C. (1996). Polymerization reactor modeling: a review of recent developments and future directions. Chemical Engineering Science, 51(10), 1637-1659.
  3. Schwab, S. T., Baur, M., Nelson, T. F., & Mecking, S. (2024). Synthesis and Deconstruction of Polyethylene-type Materials. Chemical Reviews, 124(5), 2327-2351.
  4. K. ROMÁN, G. ZSOLDOS. PVC/LDPE Blends: Relationship Between Thermal/Mechanical Properties, Structure and Blend Behaviour. (IJEMS) Vol. 4. (2019). No. 1
  5. N. Sombatsompop – K. Sungsanit – C. Thongpin (2004) Structural changes of PVC in PVC/LDPE melt- blends: Effects of LDPE content and number of extrusions. Polymer Engineering and Science. 44 (3) pp. 487–495.
  6. Thongpin C, Santavitee O, Degradation mechanism and mechanical properties of PVC in PVCPE melt blends: effects of molecular architecture, content, and MFI of PE, J Vinyl Addit Technol, 12, 115-123, 2006.
  7. Zarraga A, Munoz ME, Pena JJ, Santamaria A, Rheological effects of the incorporation of chlorinated polyethylene compatibilizers in a HDPE/PVC blend, Polym Eng Sci, 41, 1893- 1902, 2001.
  8. Zarraga A, Munoz ME, Pena JJ, Santamaria A, The role of a dechlorinated PVC as compatibiliser for PVC/polyethylene blends, Polym Bull, 48, 283-290, 2002.
  9. Wang C, Zhang Y, Zhang Y, Effect of alkyl quaternary ammonium on processing discoloration of melt-intercalated PVC-montmorillonite composites, Polym Test, 23, 299-306, 2004.
  10. Walid H. Awad a , Gu¨nter Beyer b , Daphne Benderly c , Wouter L. Ijdo c , Ponusa Songtipya d,e , Maria del Mar Jimenez-Gasco e , E. Manias d,*, Charles A. Wilkie a,* Material properties of nanoclay PVC composites. Polymer 50 (2009) 1857–1867.
  11. Awal A, Ghosh SB, Sain M. Thermal properties and spectral characterization of wood pulp reinforced bio-composite fibers. J Them Anal Calorim 2010;99: 695–701.

In this study, the morphological and thermal properties of a blend consisting of 75% polyvinyl chloride (PVC) and 25% low-density polyethylene (LDPE), reinforced with nano-refractory bricks (NRB) at varying ratios (1%, 3%, 5%, and 7%), were prepared and investigated. The objective was to enhance the blend’s thermal stability and surface structure homogeneity. The morphological structure of the prepared samples was analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The obtained images revealed that the nano-refractory brick particles remained predominantly within the PVC phase, resulting in an increased composite density without significantly affecting the LDPE phase. This suggests that the overall morphology of the composite is largely unaffected by the presence of the nano-refractory bricks. From a thermal perspective, thermogravimetric analysis (TGA/DTG) was conducted on all samples from room temperature up to 600 °C at a heating rate of 10 °C/min. FTIR and TGA results indicated that the decomposition onset temperature shifted to higher values due to the presence of nano-refractory bricks, with the most pronounced shift observed in the sample containing 3% reinforcement. Additionally, the rate of mass loss was reduced. These findings demonstrate that reinforcing the PVC/LDPE blend with nano-refractory bricks improves its performance, making it more suitable for applications that demand enhanced thermal and mechanical properties, such as those in the construction and electronics industries.

Keywords : Nano-Refractory Bricks, Low Density Polyethylene, Polymer, Thermal Properties.

CALL FOR PAPERS


Paper Submission Last Date
30 - June - 2025

Paper Review Notification
In 2-3 Days

Paper Publishing
In 2-3 Days

Video Explanation for Published paper

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe