Authors :
Olugbenga Oludayo Oluwasina; Osaretin Edwin Omoruyi; Gbenga Emmanuel Adekayero; Olabiyi Julius Akinwumi; Adebisi Olayinka Akinola; Babatunde Abraham Okunlol; Labunmi Lajide
Volume/Issue :
Volume 9 - 2024, Issue 5 - May
Google Scholar :
https://tinyurl.com/yhxfythc
Scribd :
https://tinyurl.com/se5c9sx9
DOI :
https://doi.org/10.38124/ijisrt/IJISRT24MAY1604
Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.
Abstract :
The environmental impact of waste plastics
and the need to meet the increased demand for energy,
coupled with the available technology for the conversion
of waste plastic to liquid fuel, triggered this research.
Montmorillonite clay was used as a green catalyst for the
pyrolysis of low-density polyethylene to liquid fuel. The
montmorillonite was calcinated at 600°C, and mixed
metal oxides were found as its chemical composition using
XRF. The common elements found in CMMR are silica
oxide (SiO2
, 51. 34%), iron (ii) oxide (Fe2O3, 16.23%),
potassium oxide (K2O, 5.03%), Aluminum oxide (Al2O3
,
19.65%) tin oxide (TiO2
, 3.00%), calcium oxide
(CaO,1.47%) and oxides of chlorides (Cl, 1.46%). The gas
chromatography-mass spectrometer analysis of the
various distillate fractions from the crude pyrolysis liquid
revealed the present various chemical differences such as
alkane, alkene, alkyne, cycloalkene, cycloalkane,
aromatic, alcohol, and ester. Analysis of the pyrolysis oil
based on the carbon range revealed the presence of
gasoline (C5-C12) (gasoline), diesel (C13-C24) and fuel oil
(>C24). The API, specific gravity and kinematic viscosity
of some of the oil confirmed them as diesel oil. The
research has demonstrated the possibility of waste
reduction and the potential of producing hydrocarbon
fuel from waste low-density polyethylene waste plastic
using pyrolysis.
Keywords :
Low-Density Polyethylene, Pyrolysis, GC-MS, XRF, Kinematic Viscosity.
References :
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The environmental impact of waste plastics
and the need to meet the increased demand for energy,
coupled with the available technology for the conversion
of waste plastic to liquid fuel, triggered this research.
Montmorillonite clay was used as a green catalyst for the
pyrolysis of low-density polyethylene to liquid fuel. The
montmorillonite was calcinated at 600°C, and mixed
metal oxides were found as its chemical composition using
XRF. The common elements found in CMMR are silica
oxide (SiO2
, 51. 34%), iron (ii) oxide (Fe2O3, 16.23%),
potassium oxide (K2O, 5.03%), Aluminum oxide (Al2O3
,
19.65%) tin oxide (TiO2
, 3.00%), calcium oxide
(CaO,1.47%) and oxides of chlorides (Cl, 1.46%). The gas
chromatography-mass spectrometer analysis of the
various distillate fractions from the crude pyrolysis liquid
revealed the present various chemical differences such as
alkane, alkene, alkyne, cycloalkene, cycloalkane,
aromatic, alcohol, and ester. Analysis of the pyrolysis oil
based on the carbon range revealed the presence of
gasoline (C5-C12) (gasoline), diesel (C13-C24) and fuel oil
(>C24). The API, specific gravity and kinematic viscosity
of some of the oil confirmed them as diesel oil. The
research has demonstrated the possibility of waste
reduction and the potential of producing hydrocarbon
fuel from waste low-density polyethylene waste plastic
using pyrolysis.
Keywords :
Low-Density Polyethylene, Pyrolysis, GC-MS, XRF, Kinematic Viscosity.