⚠ Official Notice: www.ijisrt.com is the official website of the International Journal of Innovative Science and Research Technology (IJISRT) Journal for research paper submission and publication. Please beware of fake or duplicate websites using the IJISRT name.



Catalysis of Sorghum Stems Potash Salt in the Conversion of Bos Taurus Zebu Slaughterhouse Fat Residues into Biodiesel


Authors : Emerentien Ly- inbé; Ngoulou Abomo; Merlin Zacharie Ayissi; Fontaine Dubois Bissaï; Francis Lénine Djanna Koffi

Volume/Issue : Volume 11 - 2026, Issue 2 - February


Google Scholar : https://tinyurl.com/ye236f3e

Scribd : https://tinyurl.com/mu8nnkar

DOI : https://doi.org/10.38124/ijisrt/26feb1487

Note : A published paper may take 4-5 working days from the publication date to appear in PlumX Metrics, Semantic Scholar, and ResearchGate.


Abstract : The production of biodiesel from edible oils and industrial catalysts increases its production cost and makes its price higher than fossil diesel. The fatty waste generated by slaughtering industries pollutes the environment and could be converted into bioenergy by various processes. Potash salt is extracted from sorghum and formulated to serve as a biocatalyst in the transesterification process of Bos Taurus Zebus tallow into biodiesel. The characterization of tallow, biocatalyst and biodiesel is carried out. The tallow has a viscosity, acidity index, density of 7.2 mm 2 /s, 5.3 mg KOH /g and 911.3 Kg/m3 respectively. The extracted potash has a potassium content of 58.3% and a pH of 10.7, characterizing the basicity of the salt. The biodiesel production yield under the constraint of a full factorial experimental design is 96.53%. The major oleic ester in the composition of the derived biodiesel is 19.65%. The viscosity and density are 5.45 mm 2 /s and 874 kg/m3 at 40°C, respectively. The cetane number is 56.7, which is higher than that of regular diesel. The obtained biodiesel can be used as an additive to fossil fuels or to power compression ignition engines.

Keywords : Biodiesel; Esterification; Full Factorial Design; Transesterification; Potash Salt.

References :

  1. Adrien, R. (2011). Contexte, impacts et débats autour de la production d'agrocarburants versus le droit à l'alimentation. Université de Sherbrooke.
  2. Alloune, R. (2017). Contribution à la mise au point d'un combustible innovant à base de culture locale non alimentaire pour les moteurs à combustion interne. Université M'hamed Bougara de Boumerdès, Département de Méc.
  3. Amal, R., Nadeem, R., Intisar, A., Rouf, H., Hussain, D., & Kousar, R. (2024). An insight into the catalytic properties and process optimization of Fe, Ni doped eggshell derived CaO for a green biodiesel synthesis from waste chicken fat. Catalysis Communications, 187, 106848 https://doi.org/10.1016/j.catcom.2024.106848.
  4. Andreo-Martinez, P., Ortiz-Martinez, V. M., Salar-Garcia, M. J., Veiga-del-Bano, J. M., Chica, A., & Quesada-Medina, J. (2022). Waste animal fats as feedstock for biodiesel production using non-catalytic supercritical alcohol transesterification: A perspective by the PRISMA methodology. Energy for Sustainable Development, 69, 150-163. https://doi.org/10.1016/j.esd.2022.06.004.
  5. Awad, S. (2011). Contribution à l’étude de la valorisation énergétique des résidus graisseux et de leur combustion dans les moteurs à combustion interne| Theses. fr. Nantes.
  6. Awad, S., Paraschiv, M., Varuvel, E. G., & Tazerout, M. (2013). Optimization of biodiesel production from animal fat residue in wastewater using response surface methodology. Bioresource technology, 129, 315-320. https://doi.org/10.1016/j.biortech.2012.11.086.
  7. Ayissi, Z., Mohand, T., Sary, A., Obounou, M., & Ohandja, L. A. (2016). Elaboration et Etude Expérimentale des Performances d’un Biocarburant Innovant à base de Deux Plantes non Comestibles Locales’. Sciences, Technologies et Développement, Edition Spéciale, 108-112.
  8. Baribeau, A., Bradley, R., Brown, P., Goodwin, J., Kihm, U., Lotero, E., . . . Taylor, D. (2007). Biodiesel from specified risk material tallow: an appraisal of TSE risks and their reduction.
  9. Bhuyan, N., Borah, M. J., Bora, N., Saikia, D., Deka, D., & Kataki, R. (2021). Heterogeneous Nanocatalytic Conversion of Waste to Biodiesel. Nano‐and Biocatalysts for Biodiesel Production, 249-277. https://doi.org/10.1002/slct.202201671.
  10. Blin, J., Villeneuve, P., Baréa, B., & Moussavou, R. W. (2016). Procédé écologique de production d'esters éthanoliques par transestérification éthanolique en catalyse enzymatique: OAPI. http://www.oapi.int/index.php/fr/brevets.
  11. Bousbaa, H., Naima, K., & Liazid, A. (2014). Valorisation des déchets de poisson en biocombustible pour moteur diesel. Le 3ème Séminaire International sur les Energies Nouvelles et Renouvelables.
  12. Chakraborty, R., & Sahu, H. (2014). Intensification of biodiesel production from waste goat tallow using infrared radiation: Process evaluation through response surface methodology and artificial neural network. Applied energy, 114, 827-836. https://doi.org/10.1016/j.apenergy.2013.04.025.
  13. Chen, K.-T., Wang, J.-X., Dai, Y.-M., Wang, P.-H., Liou, C.-Y., Nien, C.-W., . . . Chen, C.-C. (2013). Rice husk ash as a catalyst precursor for biodiesel production. Journal of the Taiwan Institute of Chemical Engineers, 44(4), 622-629. https://doi.org/10.1016/j.jtice.2013.01.006.
  14. Escobar, J. C., Lora, E. S., Venturini, O. J., Yáñez, E. E., Castillo, E. F., & Almazan, O. (2009). Biofuels: environment, technology and food security. Renewable and sustainable energy reviews, 13(6-7), 1275-1287. https://doi.org/10.1016/j.rser.2008.08.014.
  15. Ezekannagha, C. B., Ude, C. N., & Onukwuli, O. D. (2017). Optimization of the methanolysis of lard oil in the production of biodiesel with response surface methodology. Egyptian Journal of Petroleum, 26(4), 1001-1011. https://doi.org/10.1016/j.ejpe.2016.12.004.
  16. Gebremariam, S. N., & Marchetti, J. M. (2018). Economics of biodiesel production. Energy Conversion and Management, 168, 74-84. https://doi.org/10.1016/j.enconman.2018.05.002.
  17. Ghadge, S. V., & Raheman, H. (2006). Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology. Bioresource technology, 97(3), 379-384. https://doi.org/10.1016/j.biortech.2005.03.014.
  18. Hasan, N., & Ratnam, M. V. (2022). Biodiesel production from waste animal fat by transesterification using H2SO4 and KOH catalysts: A study of physiochemical properties. International Journal of Chemical Engineering, 2022(1), 6932320. https://doi.org/10.1155/2022/6932320.
  19. Jambulingam, R., Srinivasan, G. R., Palani, S., Munir, M., Saeed, M., & Mohanam, A. (2020). Process optimization of biodiesel production from waste beef tallow using ethanol as co-solvent. SN Applied Sciences, 2, 1-18. https://doi.org/10.1007/s42452-020-03243-7.
  20. Kellou, H., & Mansour, R. (2016). Synthèse et caractérisation du biodiesel issu d'une huile de friture usagée.
  21. Khiari, K. (2016). Contribution à l'étude des propriétés thermo-physiques des biocarburants de seconde génération et leur influence sur le comportement des moteurs. Ecole des Mines de Nantes.
  22. Ma, Y., Bi, Q., Li, G., Liu, X., Fu, G., Zhao, Y., & Wang, L. (2020). Provenance variations in kernel oil content, fatty acid profile and biodiesel properties of Xanthoceras sorbifolium Bunge in northern China. Industrial crops and products, 151, 112487. https://doi.org/10.1016/j.indcrop.2020.112487.
  23. MRAD, N., ALOUI, F., TAZEROUT, M., & NASRALLAH, S. B. (2010). Valorisation des graisses animales comme biocombustibles pour moteurs diesel. Paper presented at the Proceedings Congress Société Française de Thermique.
  24. Normand, X., & Treil, A. (1978). L'Industrie du raffinage du pétrole: leçons sommaires (Vol. 2): Editions Technip.
  25. Okwundu, O. S., El-Shazly, A. H., & Elkady, M. (2019). Comparative effect of reaction time on biodiesel production from low free fatty acid beef tallow: a definition of product yield. SN Applied Sciences, 1, 1-12. https://doi.org/10.1007/s42452-018-0145-1.
  26. Okwundu, O. S., El-Shazly, A. H., Elkady, M. F., & Shaaban, W. M. (2019). Response surface modeling and optimization of heterogeneous methanolysis of beef tallow. Paper presented at the AIP Conference Proceedings. https://doi.org/10.1063/1.5116930.
  27. Olubunmi, B. E., Alade, A. F., Ebhodaghe, S. O., & Oladapo, O. T. (2022). Optimization and kinetic study of biodiesel production from beef tallow using calcium oxide as a heterogeneous and recyclable catalyst. Energy Conversion and Management: X, 14, 100221. https://doi.org/10.1016/j.ecmx.2022.100221.
  28. OUEDRAOGO, N., SAWADOGO, N., NIKIEMA, M. P., KOURAOGO, I., SAWADOGO, A. P., & NEBIE, B. (2023). Performance agronomique et mise en évidence de la distinction inter-variétale, de l’homogénéité et de la stabilité intra-variétale de sept variétés de sorgho au Burkina Faso. Sciences Naturelles et Appliquées, 42(2 (1)), 89-106.
  29. Perrin-Guyomard, A., Bruneau, M., Mourand, G., Kempf, I., Cuzzucoli, D., & Granier, S. (2022). Dispositif français de surveillance de la résistance aux antibiotiques des bactéries zoonotiques et commensales isolées chez les animaux d’élevage et dans les denrées alimentaires d’origine animale. Bulletin épidémiologique, 96(3), 1-12.
  30. Prajapati, P., Shrivastava, S., Sharma, V., Srivastava, P., Shankhwar, V., Sharma, A., . . . Agarwal, D. (2023). Karanja seed shell ash: A sustainable green heterogeneous catalyst for biodiesel production. Results in Engineering, 18, 101063. https://doi.org/10.1016/j.rineng.2023.101063.
  31. Rabo, Y., Sadikou, I. B. M., & Mahamane, A. (2024). Effets de Faidherbia albida (Delile) sur des Paramètres de Croissance et de Rendement du Mil (Pennisetum glaucum (L.) R. Br) en Milieu Paysan dans la Commune de Tibiri (Niger). ESI Preprints, 20(6).
  32. Rapport, I. Les biocarburants et la faim dans le monde. www.i-sis.org.uk/biofuelsAndWorldHunger.php.
  33. Richard, R. (2011). Transestérification éthanolique d'huile végétale dans des microréacteurs: transposition du batch au continu.
  34. Saravanan, R., Sathish, T., Ağbulut, Ü., Sathyamurthy, R., Sharma, P., Linul, E., & Asif, M. (2024). Waste bull bone based reusable and biodegradable heterogeneous catalyst for alternate fuel production from WCO, and investigation of its usability as fuel substitute. Fuel, 355, 129436. https://doi.org/10.1016/j.fuel.2023.129436.
  35. Seffati, K., Honarvar, B., Esmaeili, H., & Esfandiari, N. (2019). Enhanced biodiesel production from chicken fat using CaO/CuFe2O4 nanocatalyst and its combination with diesel to improve fuel properties. Fuel, 235, 1238-1244. https://doi.org/10.1016/j.fuel.2018.08.118.
  36. Serge, R. K., Armand, A. B., Richard, T., Augustin, G., & Albert, N. (2023). Physicochemical Properties and Fertility Level of the Vertisols Surface Horizons for muskuwaari [Sorghum bicolor (L.) Moench] Cultivation in the Sudano-Sahelian zone of Cameroon. Journal of Agriculture and Ecology Research International, 24(5), 142-161.
  37. Sharma, K., Castello, D., Haider, M. S., Pedersen, T. H., & Rosendahl, L. A. (2021). Continuous co-processing of HTL bio-oil with renewable feed for drop-in biofuels production for sustainable refinery processes. Fuel, 306, 121579. https://doi.org/10.1016/j.fuel.2021.121579.
  38. Soares Dias, A. P., Ramos, M., Catarino, M., Puna, J., & Gomes, J. (2020). Solvent assisted biodiesel production by co-processing beef tallow and soybean oil over calcium catalysts. Waste and Biomass Valorization, 11, 6249-6259. https://doi.org/10.1007/s12649-019-00903-7.
  39. Suleiman, I. A., Abubakar, S., Kaisan, M. U., Magaji, S., Abubakar, A. S., Shitu, S., . . . Umaru, S. (2020). Production and performance appraisal of biodiesel derived from used cooking oil on compression ignition engine. FUDMA Journal of Sciences, 4(2), 658-672. https://doi.org/10.33003/fjs-2020-0402-240.
  40. Suwannapa, P., & Tippayawong, N. (2017). Optimization of two-step biodiesel production from beef tallow with microwave heating. Chemical Engineering Communications, 204(5), 618-624. https://doi.org/10.1080/00986445.2017.1294585.
  41. Tarabet, L., Hanchi, S., & Tazerout, M. Conversion d’une l’Huile Végétale en Carburant pour le Moteur Diesel.
  42. Toldrá-Reig, F., Mora, L., & Toldrá, F. (2020). Trends in biodiesel production from animal fat waste. Applied Sciences, 10(10), 3644. https://doi.org/10.3390/app10103644.
  43. Verma, P., & Sharma, M. (2016). Comparative analysis of effect of methanol and ethanol on Karanja biodiesel production and its optimisation. Fuel, 180, 164-174. https://doi.org/10.1016/j.fuel.2016.04.035.
  44. Woo, D. G., & Kim, T. H. (2019). Fuel properties of biodiesel produced from beef-tallow and corn oil blends based on the variation in the fatty acid methyl ester composition. Korean Journal of Agricultural Science, 46(4), 941-953. https://doi.org/10.7744/kjoas.20190076.
  45. Zhao, X., Xu, G., Yu, Y., Yan, X., & Zhang, B. (2013). Optimization of transesterification of beef tallow for biodiesel production catalyzed by solid catalysts. Transactions of the Chinese Society of Agricultural Engineering, 29(17), 196-203.

The production of biodiesel from edible oils and industrial catalysts increases its production cost and makes its price higher than fossil diesel. The fatty waste generated by slaughtering industries pollutes the environment and could be converted into bioenergy by various processes. Potash salt is extracted from sorghum and formulated to serve as a biocatalyst in the transesterification process of Bos Taurus Zebus tallow into biodiesel. The characterization of tallow, biocatalyst and biodiesel is carried out. The tallow has a viscosity, acidity index, density of 7.2 mm 2 /s, 5.3 mg KOH /g and 911.3 Kg/m3 respectively. The extracted potash has a potassium content of 58.3% and a pH of 10.7, characterizing the basicity of the salt. The biodiesel production yield under the constraint of a full factorial experimental design is 96.53%. The major oleic ester in the composition of the derived biodiesel is 19.65%. The viscosity and density are 5.45 mm 2 /s and 874 kg/m3 at 40°C, respectively. The cetane number is 56.7, which is higher than that of regular diesel. The obtained biodiesel can be used as an additive to fossil fuels or to power compression ignition engines.

Keywords : Biodiesel; Esterification; Full Factorial Design; Transesterification; Potash Salt.

Paper Submission Last Date
31 - March - 2026

SUBMIT YOUR PAPER CALL FOR PAPERS
Video Explanation for Published paper

Never miss an update from Papermashup

Get notified about the latest tutorials and downloads.

Subscribe by Email

Get alerts directly into your inbox after each post and stay updated.
Subscribe
OR

Subscribe by RSS

Add our RSS to your feedreader to get regular updates from us.
Subscribe