A Review on Lithium Removal Techniques in Aqueous Environment


Authors : Augustus Newton Ebelegi

Volume/Issue : Volume 10 - 2025, Issue 12 - December


Google Scholar : https://tinyurl.com/49d397hn

Scribd : https://tinyurl.com/3mw7j59f

DOI : https://doi.org/10.38124/ijisrt/25dec352

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Abstract : The growing demand for lithium in renewable energy technologies, such as batteries for electric vehicles and energy storage systems, has led to an increase in its extraction and processing activities, resulting in elevated levels of lithium in industrial wastewater. The effective removal of lithium from wastewater is crucial to mitigate its environmental impact and recover this valuable resource. This review provides a comprehensive overview of the current methods for lithium removal from industrial effluents, including chemical precipitation, ion exchange, adsorption, membrane technologies, and electrochemical processes. It evaluates these methods in terms of efficiency, cost, environmental impact, and scalability. Additionally, emerging approaches such as bio-remediation and hybrid techniques are discussed, highlighting their potential for enhanced lithium recovery. The review also identifies knowledge gaps and future research directions to optimize lithium removal and recovery processes. By consolidating current advancements and challenges, this work aims to guide researchers and industry stakeholders in developing sustainable solutions for lithium management in industrial wastewater.

Keywords : Lithium, Wastewater, Bio-Remediation, Industrial, Energy.

References :

  1. Narasimhan, R.; Yoon, S. W.; Louie, S. G. (2006). "Electron correlation in semiconductors and insulators: Band gaps and quasiparticle energies". Phys. Rev. B 74 (16): 161101.)
  2. D. Brown, (1987)"Atomic Masses and Fundamental Constants 4," Journal of Physical and Chemical Reference Data, 6(4),
  3. Geddes, J. R.; Burgess, S.; Hawton, K.; Jamison, K.; Goodwin, G. M. (2004). "Long-term lithium therapy for bipolar disorder: systematic review and meta-analysis of randomized controlled trials". Am J Psychiatry 161 (2): 217–222.)
  4. Nathalie Bonnemains, Séverine Casalis, et al., "Comparison of Different Lithium Compounds in the Formation of Greases", Lubricants, 2014, 2(4), 237-250)
  5. P. Hubert and W. Hümmer, (2002.) "Lithium and Lithium Compounds," in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH,
  6. Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds" CRC Handbook of Chemistry and Physics (PDF) (86th ed.). CRC Press. ISBN 0-8493-0486-5.).
  7. Ooi, K., Miyai, Y., Katoh, S., Maeda, H., & Abe, M. (1988). The pH titration study of lithium-ion adsorption on. LAMBDA. -MnO2. Bulletin of the Chemical Society of Japan61(2), 407-411.
  8. Murphy, O., & Haji, M. N. (2022). A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions. Frontiers in Chemical Engineering4, 1008680.
  9. Miller, S. A., & Farrow, C. (2019). The environmental and economic implications of solar evaporation for lithium extraction. Journal of Environmental Management, 241, 469-475.
  10. Peng, Y., & Manthiram, A. (2020). Environmental impact of lithium extraction from hard rock sources. Resources, Conservation and Recycling, 162, 104988.
  11. Shao, L., & Chen, G. (2021). Advances in direct lithium extraction from brines: Challenges and future perspectives. Renewable and Sustainable Energy Reviews, 150, 111514.
  12. Gaines, L. (2018). Lithium-ion battery recycling processes: Research towards a sustainable future. Journal of Environmental Management, 232, 444-456.
  13. Harper, G., Sommerville, R., Kendrick, E., Driscoll, L., Slater, P., Stolkin, R., ... & Anderson, P. (2019). Recycling lithium-ion batteries from electric vehicles. Nature, 575(7781), 75-86.
  14. Zeng, X., Li, J., & Singh, N. (2014). Recycling of spent lithium-ion battery: A critical review. Critical Reviews in Environmental Science and Technology, 44(10), 1129-1165.
  15. Kim, D., Ahn, J., & Shin, W. (2020). Recent advances in adsorbents for lithium recovery from aqueous environments. Journal of Materials Chemistry A, 8(24), 11914-11935.
  16. Li, J., Zhang, Y., Zhao, Y., & Wang, X. (2017). Advances in lithium precipitation processes: Mechanisms, challenges, and solutions. Chemical Engineering Journal, 320, 308-321.
  17. Kumar, S., Gupta, S., & Sharma, A. (2020). Lithium uptake in hyperaccumulator plants: Mechanisms and applications. Journal of Environmental Management, 256, 109945.
  18. Liu, Z., Zhang, H., & Wang, Y. (2022). Microalgal bioaccumulation of lithium: A review of mechanisms and applications. Bioresource Technology, 344, 126215.
  19. Wang, X., Li, Y., & Chen, J. (2021). Biosorption of lithium from aqueous solutions using microbial biomass: Advances and perspectives. Chemosphere, 275, 130108.
  20. Su, X., Tan, S., & Chen, X. (2019). Electrochemical methods for lithium recovery from aqueous systems: A review. Separation and Purification Technology, 219, 227-243.
  21. Xie, X., Wang, M., Wang, X., Liu, J., & Zhou, J. (2019). Ion exchange processes for lithium recovery from aqueous solutions: A review. Separation and Purification Reviews, 48(1), 22-43.
  22. Zhao, S., Wang, H., & Zhang, J. (2018). Membrane-based lithium recovery from aqueous solutions: Current status and future prospects. Journal of Membrane Science, 565, 22-35.

The growing demand for lithium in renewable energy technologies, such as batteries for electric vehicles and energy storage systems, has led to an increase in its extraction and processing activities, resulting in elevated levels of lithium in industrial wastewater. The effective removal of lithium from wastewater is crucial to mitigate its environmental impact and recover this valuable resource. This review provides a comprehensive overview of the current methods for lithium removal from industrial effluents, including chemical precipitation, ion exchange, adsorption, membrane technologies, and electrochemical processes. It evaluates these methods in terms of efficiency, cost, environmental impact, and scalability. Additionally, emerging approaches such as bio-remediation and hybrid techniques are discussed, highlighting their potential for enhanced lithium recovery. The review also identifies knowledge gaps and future research directions to optimize lithium removal and recovery processes. By consolidating current advancements and challenges, this work aims to guide researchers and industry stakeholders in developing sustainable solutions for lithium management in industrial wastewater.

Keywords : Lithium, Wastewater, Bio-Remediation, Industrial, Energy.

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Paper Submission Last Date
31 - December - 2025

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